The Laws of Thermodynamics: A Very Short Introduction

Peter Atkins’ “The Laws of Thermodynamics: A Very Short Introduction”, (Oxford University Press, 2010) is yet another in a series of thumbnail sketches that give readers, students, and even potential scholars fundamental information about subjects many will know little or nothing about, but which will contribute immeasurably to the fund of knowledge and information that they may already have – things that may have heard about, may know something about, but not in any great detail, and which just might connect with the knowledge they may already have, reinforcing and adding both depth and precision to what they already know and use in their daily lives.So it is with this slim little book that arrived in this morning’s mail. Unwrapped and in hand by noon, and read cover to cover by 3:00 p.m., 94 pages of good solid information tucked inside its colorful covers, and including no fewer than 22 charts, graphs, and illustrations making clear the author’s central points. This is a book that I anticipate referring to again and again. And, I was delighted with the conversational way in which Atkins makes his points, making comparisons and figures of speech that are readily understood. Several times I caught myself murmuring ‘Oh yeah. So that’s the way it works;’ or,’ that’s what it means’.Beginning with the concept of temperature (the Zeroth Law) Atkins takes us into the realm of temperature equilibrium, pressure, heat transfer, modes of measurement, molecules and their response to energy states.Then, in Chapter 2, Adkins introduces us to the First Law, the conservation of energy, and how it works: path independence, what is meant by ‘work’, and he transfer as a mode of transferring energy from one set of molecules to another, and what happens then. He then tells us what happens during a process known as enthalpy as a process in which energy transfers within the system, and why energy can neither be created nor destroyed because time cannot be reversed.In Chapter 3, Atkins discusses what is meant by ‘entropy’, and how entropy affects a system’s internal energy. This leads into a discussion of heat engines and their relative efficiency; why an engine that uses heat to create motive power needs also to have a ‘cold sink’ to dissipate accumulated heat because it is the differential in heat gradient that makes the engine work as intended in a cyclic process.I further learned that entropy is a measure of the ‘quality’ of stored energy. Basically, action seems to be saying that as energy is transferred from its initial repository for potential use the release and flow of energy permeates the entire system and its surroundings; some of that energy performs useful work while the remainder dissipates into the system’s outer reaches and beyond as either heat energy or light, as with the furnace, or a celestial object, like the sun.Entropy is also described as a measure of disorder as substances representing stored energy (i.e., petroleum or coal) are consumed through the process of oxidation and decomposition into simpler, entered substances for which their energy potential have been depleted or removed (coal ash or carbon dioxide and water vapor). In popular parlance entropy has been described as a measure of disorder, or is the tendency of complex objects or substances to degrade or decompose into their constituent parts. That appears to be an extrapolation of the basic concept; but specific to thermodynamics, not necessarily accurate.Atkins then describes how refrigeration and heat pumps operate, and extrapolates from steam engines to chemical and biological changes in food items that essentially replicate the same effects.In Chapter 4, Atkins describes the cost of converting stored energy into ‘work’ or life-sustaining energy – the so-called Gibbs energy that are accomplished through biologic processes alone. He then go on to describe the mechanics of freezing under conditions of physical changes along the temperature gradient running from a gas or vapor through a liquid form into a solid.Chapter 5 speaks to the unattainability of absolute zero temperature and superconductivity. Atkins notes of the composition of matter and the nature of the electromagnetic spectrum combined to make attainment of 0° temperature on an absolute scale and impossibility. He states: “simply put, the entropy of all perfectly crystalline substances at zero temperature is zero”. Whether non-cyclic processes can eventually reach her approximate -273° Kelvin may be theoretically possible; but the process by which that would necessarily occur is subject to a power law, and with the logarithmic curve expanding into infinity. In effect, that would be like attempting to exceed the speed of light; and the fundamental nature of the universe will not allow that.So, there we have it. Peter Atkins concise, neat little book is an absolute gem. I heartily recommend it.

I'm a big fan of the "A Very Short Introduction" series, wanted to review some basic physics (a longstanding interest), and this seemed like a nice concise review of the basics. I was not only pleased but delighted with the book. With respect to content, it provides a good overview at an introductory level (more precisely, at an ambitious high school or introductory college level). There are excellent chapters on each of the four laws of thermodynamics: the zeroth law that addresses the concept of temperature (the funny numbering is a historical artifact in that it was not named until the 20th century); the first law (on conservation of energy); the second law (on entropy, one of the most important laws in all of science); and the third law (which holds that nothing can be cooled or cool to absolute zero). There is also a fine chapter on energy and work. What distinguishes this little book from others, however, has more to do with style than content. I was not familiar with the author, Peter Atkins, until downloading this recently; after reading it, I immediately downloaded three of his other books mainly because I enjoy his writing so much. (One of the other books is Galileo's Finger: The Ten Great Ideas of Science, which has suberb chapters on evolution, DNA, energy, entropy, atoms, quantum physics, cosmology, and other things.) He is a gifted educator who explains complex concepts in clear, plain language with an emphasis on basic principles and minimal math (which can either be studied or ignored at the reader's discretion). Moreover, he is able to make the material come alive by drawing on the history of physics, describing how various laws and principles came to be discovered, and by explaining their practical significance. For instance, he explains how the second law governs everyday experiences such as cars and refrigerators, and, more importantly, that it has more far-reaching implications, one of which is that it is impossible to build a perpetual motion machine. In short, the book provides an excellent conceptual framework for what is usually considered a difficult subject, simplifying the material by presenting it in bite size pieces.In conclusion: (1) For dabblers like me, this is a superb introduction and summary; (2) For students who want an introduction to the basic concepts, this is for you -- no one should take an introductory physics course that includes thermodynamics without reading this.

Si piensas entrar al mundo de la termodinámica, este libro es una excelente opción. Sin embargo, debes estar seguro de entrañar en las leyes de la termodinámica, ya que a pesar que el autor trata de redactar de manera simple y nada técnica, es una lectura de mucha reflexión sobre lo que se lee. Es de mucha ayuda buscar videos en internet a la vez que se lee el libro.

War zur Auffrischung der Uni-Vorlesung vor 40 Jahren gedacht. Erfüllt seinen Zweck. Nicht nebenbei lesbar, aber nicht übermäßig viel schwieriges Material, verständlich geschrieben.

I had studied these topics in school a long time back, and thought to give this book a try because it was written by a well regarded chemist and is just 100 pages. I was not expecting much from such a small book, but was pleasantly surprised. The concepts are very clearly presented (there are diagrams too), and higher level physics is carefully skipped at places by giving appropriate intuition. The book is short, but I think the coverage is pretty good. Also, there are some examples towards end of the book about how the concepts apply to chemical reactions etc.I wish all physics introduction books are written like this. I'd highly recommend this book.

熱力学の基礎を勉強したい方にお勧めします。とても分かりやすいです。

In keeping with a number of Kindle text books this one also has not been proofread. I got as far as page 29 where there is an obvious error in the equation relating enthalpy to internal energy, pressure and volume. As this book is aimed at people who have little to no prior knowledge of thermodynamics this is a major problem. I have given up on this book and would strongly recommend that you don't buy it. I would have given this book zero stars but that option is not available